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  • Spectroscopic measurements of stratospheric gases Nitrogen Dioxide (NO2), Chlorine Dioxide (OCIO), Bromine Oxide (BrO) and Ozone (O3) using scattered sunlight. Airyx and Envimeas: A dual MAX-DOAS UV/visible wavelength diode array spectrometer is deployed to measure of ozone (O3), nitrogen dioxide (NO2), chlorine dioxide (OClO) and bromine oxide (BrO). The instrument is a similar instrument to that of EnviMeas, and produces overlapping datasets with ADAS-2. Fixed azimuth direction, same as the Antarctic Diode Array spectrometer. System 2 (ADAS-2). The data are currently being held internally by NIWA. “Raw” data are times and recorded spectra of scattered light for several viewing directions. “Derived” data are column amount of NO2, OClO, BrO and O3, which can be split into tropospheric and stratospheric parts. This technique is sometimes referred to as MAX-DOAS Multiple-Axis Dual Optical Absorption Spectrometry. This work is carried out in collaboration the University of Heidelberg. ADAS2, Envimeas and Airyx measurements: UV/visible Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) diode array spectrometers making measurements of ozone (O3), nitrogen dioxide (NO2), chlorine dioxide (OClO) and bromine oxide (BrO). JY: A scanning grating UV/Vis monochromator taking measurements of total slant column of NO2 and Ozone using scattered zenith sunlight. ADAS: A CCD grating UV/Vis grating Acton spectrometer making measurements of total slant column NO2, BrO, OClO and ozone made using scattered light zenith sunlight. Pandora: Direct sun UV/Vis measurements of ozone and NO2. Campaign to test feasibility of long term deployment at Arrival Heights. Instrument timeline JY: 1982 -2023 ADAS: 1993 - 2017 ADAS2: 1998 - present Pandora: 2015 Aug – Oct. Airyx & Envimeas : 2018 – present O3, OCIO and BrO data are in the process of being archived - please contact Richard Querel for data access. NO2 data is available via the "GET DATA" link. GET DATA: https://www-air.larc.nasa.gov/missions/ndacc/data.html?station=arrival.heights